Chemoenzymatic asymmetric synthesis of harzia lactone A stereomers |
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| Authors: | Abha N. Kumar Suchitra Bhatt Subrata Chattopadhyay |
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| Affiliation: | Bio-Organic Division, Bhabha Atomic Research Centre, Mumbai 400 085, India |
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| Abstract: | A facile chemoenzymatic synthesis of the harzia lactone A enantiomers was developed. A lipase-catalyzed acylation and an enantio-controlled substrate and reagent-controlled Sharpless’ asymmetric dihydroxylation are the key features of the synthesis. |
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