Highly enantioselective Ir-catalyzed hydrogenation of exocyclic enamines |
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Authors: | Xiao-Bing Wang Da-Wei Wang Sheng-Mei Lu Chang-Bin Yu Yong-Gui Zhou |
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Affiliation: | State Key of Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China |
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Abstract: | [Ir(COD)Cl]2/MeO-BiPhep/I2 catalyst system is highly effective for the asymmetric hydrogenation of exocyclic enamines with high enantioselectivities (up to 96% ee). |
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