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Highly enantioselective Ir-catalyzed hydrogenation of exocyclic enamines
Authors:Xiao-Bing Wang  Da-Wei Wang  Sheng-Mei Lu  Chang-Bin Yu  Yong-Gui Zhou
Institution:State Key of Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China
Abstract:Ir(COD)Cl]2/MeO-BiPhep/I2 catalyst system is highly effective for the asymmetric hydrogenation of exocyclic enamines with high enantioselectivities (up to 96% ee).
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