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Enantioselective aldol reaction of silyl ketene acetals promoted by a Lewis base-activated Lewis acid catalyst |
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| Authors: | Yasushi Shimoda Teppei Tando Shunsuke Kotani Masaharu Sugiura Makoto Nakajima |
| Affiliation: | 1. Faculty of Medical and Pharmaceutical Sciences, Kumamoto University, Kumamoto 862-0973, Japan;2. Priority Organization for Innovation and Excellence, Kumamoto University, Kumamoto 862-0973, Japan |
| Abstract: | The enantioselective aldol reaction of a silyl ketene acetal was promoted by chiral phosphine oxide-activated tetrachlorosilane to afford the corresponding adduct in high yield with moderate enantioselectivity. |
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