Transsilylation reactions in esters and ethers of the silanols synthesis of oxasilacycloalkanes |
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| Authors: | V. F. Mironov N. S. Fedotov V. L. Kozlikov |
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| Affiliation: | (1) State Scientific-Research Institute for the Chemistry and Technology of Heteroorganic Compounds, Moscow |
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| Abstract: | An equilibrium reaction of the exchange of silyl radicals taking place between organylchlorosilanes and acyloxy- and alkoxysilanes has been found. In the rase of alkenyloxytrimethylsilane and chloro-H-silanes. in addition to the transsilylation reaction, intramolecular hydrosilyation takes place, leading to the formation of oxasilacycloalkanes. |
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