Electrochemical reduction of phenylethynyl halides and related compounds |
| |
| Authors: | S M Peregudova L I Denisovich N A Ustynyuk L I Leont'eva V N Vinogradova T V Filatova |
| |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| |
| Abstract: | Reduction of phenylethynyl halides PhC CHal (Hal = I (1), Br (2), Cl (3)), diiodoacetylene (4), (phenylethynyl)triphenylphosphonium bromide (5), and related compounds in THF was studied by means of cyclic voltammetry using a glassy-carbon electrode. Compounds1–5 are reduced with cleavage of the C-Hal bond, and the reduction potentials increase in the order3 <2 <1 <4 <5.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2055–2057, October, 1995. |
| |
| Keywords: | electroreduction alkynyl halides |
| 本文献已被 SpringerLink 等数据库收录！ |
|
