Some aspects of diffusion: fluctuations in reaction diffusion,and geometric influences in nonuniform media |
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Authors: | H L Frisch J C Kimball |
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Institution: | (1) Departments of Chemistry and Physics, State University of New York, 12222 Albany, NY, USA |
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Abstract: | Summary We deal with two diffusion problems: Space-integrated conserved entities characterizing very fast - diffusion - controlled reactions, such as time lags, etc. are universal. They are given by relationships which do not reflect the failure of the mean field hydrodynamic equations. We present another application which does not reflect this failure, for determining the surface flux via a diffusion controlled reaction producing a colored product. Another anomalous diffusion process we considered is transport through cellular materials whose cell sizes are highly nonuniform. We have analyzed the effects of extreme nonuniformity by considering fractal-like models of cellular solids. The diffusion current through these models can exhibit anomalous time-dependencies which are not predicted by the diffusion equation. In particular, it is shown that the initial diffusion current can be characterized by a power-law dependence on the time. Furthermore, the exponent of the power law is given in terms of the distribution of cell sizes in the fractal-like cellular solid. |
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Keywords: | Diffusion-reaction Transport Time lag Fractal foams Low density microcellular materials |
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