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The chromatography of metals on DEAE-cellulose layers in phosphoric acid media
Authors:Rokuro Kuroda  Takaaki Kondo
Abstract:The adsorption behaviour of forty-eight metals on DEAE-cellulose thin layers has been examined in aqueous phosphoric acid media. RF values are given as a function of phosphoric acid concentration over the range 0.01–1.0 M and are compared with those obtained in a similar manner with a crystalline cellulose, Avicel SF. Particularly strong retention on DEAE-cellulose occurred for Mo(VI), W(VI), Re(VII), the platinum group metals, Au(III) and Bi(III). Weak to moderate retention was also observed for several metals, such as V(V), Fe(III), Se(IV), In(III), the rare earths and U(VI), at lower concentrations of phosphoric acid (<0.1 M).
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