| Synthesis and Crystal Structure of MnSm_4(SiO_4)_3O |
| |
| 引用本文： | Chi Li-Sheng,Deng Shui-Quan, Zhuang Hong-Hui,Huang Jin-Shun,(State Hey laboratory of Structural Chemistry,Fujian institute of Research on the Structure of Matter,Chinese Academy of Scimces,Fuzhou,Fujian 350002,P.R.China). Synthesis and Crystal Structure of MnSm_4(SiO_4)_3O[J]. 结构化学, 1996, 0(2) |
| |
| 作者姓名： | Chi Li-Sheng Deng Shui-Quan Zhuang Hong-Hui Huang Jin-Shun (State Hey laboratory of Structural Chemistry Fujian institute of Research on the Structure of Matter Chinese Academy of Scimces Fuzhou Fujian 350002 P.R.China) |
| |
| 作者单位： | State Hey laboratory of Structural Chemistry，Fujian institute of Research on the Structure of Matter，Chinese Academy of Scimces，Fuzhou，Fujian 350002，P.R.China |
| |
| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＭｎＳｍ_４（ＳｉＯ_４）_３Ｏ￥ＣｈｉＬｉ－Ｓｈｅｎｇ；ＤｅｎｇＳｈｕｉ－Ｑｕａｎ；ＺｈｕａｎｇＨｏｎｇ－Ｈｕｉ；ＨｕａｎｇＪｉｎ－Ｓｈｕｎ；（ＳｔａｔｅＨｅｙｌａｂｏｒａｔｏｒｙｏｆＳｔｒ?..
|
Synthesis and Crystal Structure of MnSm_4(SiO_4)_3O |
| |
| Chi Li-Sheng,Deng Shui-Quan, Zhuang Hong-Hui,Huang Jin-Shun,. Synthesis and Crystal Structure of MnSm_4(SiO_4)_3O[J]. Chinese Journal of Structural Chemistry, 1996, 0(2) |
| |
| Authors: | Chi Li-Sheng Deng Shui-Quan Zhuang Hong-Hui Huang Jin-Shun |
| |
| Abstract: | MnSm4(SiO4)3O,Mr=948.81,hexagonal,P63/m,a =9.444(2),c=6.829(2),V=527.23,Z=2,Dc=2.99 g.cm-3,λ(MoKa)=0.71073 A,μ=117.8 cm-1,F(000)=419,R=0. 048,Rω=0.055 for 982 observed unique reflections.The compound is isomorphous with natural apatite.The 6h lattice site is occupied by Sm atom with a distorted pentagonal bipyramid coordination geometry,and the 4f site by M(M =1/2Sm+ 1/2Mn) atom in a tricapped trigonal prismatic coordination configuration. |
| |
| Keywords: | rare earth compound apatite analog crystal structure |
| 本文献已被 CNKI 等数据库收录！ |
|
