| N-(p-乙烯氧基苯基)咔唑的合成和聚合 |
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| 引用本文： | 叶大铿,卢开涛.N-(p-乙烯氧基苯基)咔唑的合成和聚合[J].高分子学报,1993,0(6):728-732. |
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| 作者姓名： | 叶大铿 卢开涛 |
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| 作者单位： | 中山大学化学系; 湖北教育学院化学系 |
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| 摘 要： | N-(p-Ethenyloxyphenyl) carbazole (NEOPC) has been synthesized by etherification of p-bromophenol with vinyl acetate, then p-bromophenyl vinyl ether reacting with carbaxole in the presence of brass power and potassium carbonate at 200℃. The product was identified by elemental analysis, 1H NMR, 13C NMR and IR spectra. NEOPC is readily polymerized by conventional catalysts of cationic polymerization, such as BF3OEt2, I2, TiCl4, AlCl3, etc. But no polymer was obtained when free radical initiators were used. The rearrangement products and/or the solvent-insoluble products in cationic polymerization of NEOPC. which may be produced by the crosslinking have been discussed.
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| 关 键 词： | 乙烯氧基 苯基 卡唑 聚合 重排聚合 |
| 收稿时间： | 1992-05-13 |
SYNTHESIS AND POLYMERIZATION OF N- (P-ETHENYLOXYPHENYL)CARBAZOLE |
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| YE Da-keng,LU Kai-tao.SYNTHESIS AND POLYMERIZATION OF N- (P-ETHENYLOXYPHENYL)CARBAZOLE[J].Acta Polymerica Sinica,1993,0(6):728-732. |
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| Authors: | YE Da-keng LU Kai-tao |
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| Institution: | Department of Chemistry; Zhongshan University; Guangzhou; Post code: 510275; Department of Chemistry; Hubei Institute of Education; Wuhan Post code: 430000 |
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