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脂质体封端CsPbX3(X=Cl,Br,I)纳米晶体的制备及在发光二极管中的应用
引用本文:王婷婷,雷宇涵,林宇娟,黄加玲,刘翠娥,郑凤英,李顺兴. 脂质体封端CsPbX3(X=Cl,Br,I)纳米晶体的制备及在发光二极管中的应用[J]. 高等学校化学学报, 2020, 41(8): 1896. DOI: 10.7503/cjcu20200182
作者姓名:王婷婷  雷宇涵  林宇娟  黄加玲  刘翠娥  郑凤英  李顺兴
作者单位:1. 闽南师范大学化学化工与环境学院, 漳州 363000;2. 现代分离分析科学与技术福建省重点实验室&污染监测与控制福建省高校重点实验室, 漳州 363000
基金项目:国家自然科学基金(批准号:21475055,201675077)资助.
摘    要:以脂质体充当表面封端配体修饰合成后的CsPbX3纳米晶体.封端CsPbX3纳米晶能保持原始形状和粒径大小,相对量子产率提升至(100±3)%,发射光谱在411~626 nm范围内可调.将其存储于空气(温度25℃,相对湿度50%)中150 d仍保持立方晶型.以DOPC-CsPbBr3为颜色转换器可制造显色指数高达91.2的白色发光二极管,应用前景广阔.

关 键 词:钙钛矿纳米晶  脂质体  表面钝化  稳定性  发光二极管  
收稿时间:2020-04-05

Preparation of Liposome-terminated CsPbX3(X=Cl,Br,I) Nanocrystals and Applications in Light-emitting Diode Devices
WANG Tingting,LEI Yuhan,LIN Yujuan,HUANG Jialing,LIU Cuie,ZHENG Fengying,LI Shunxing. Preparation of Liposome-terminated CsPbX3(X=Cl,Br,I) Nanocrystals and Applications in Light-emitting Diode Devices[J]. Chemical Research In Chinese Universities, 2020, 41(8): 1896. DOI: 10.7503/cjcu20200182
Authors:WANG Tingting  LEI Yuhan  LIN Yujuan  HUANG Jialing  LIU Cuie  ZHENG Fengying  LI Shunxing
Affiliation:1. College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000, China;2. Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology&Pollution Monitoring and Control, Minnan Normal University, Zhangzhou 363000, China
Abstract:Liposomes are used as surface-capped ligands to modify the synthesized CsPbX3 nanocrystals. The capped CsPbX3 nanocrystals maintain their original shape and particle size, improve relative quantum yield by (100±3)%, and have adjustable emission spectrum in the range of 411-626 nm. It maintains cubic crystal form when stored in air(temperature 25℃, relative humidity 50%) for 150 d. The DOPC-CsPbBr3 NCs are used as a color converter to make white light-emitting diodes with a color rendering index of 91.2%, which has a broad application prospect.
Keywords:Perovskite nanocrystals  Liposomes  Surface passivation  Stability  Light-emitting diode  
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