首页 | 本学科首页   官方微博 | 高级检索  
     


On microscopical derivation of Lorentz-Lorenz formula
Authors:E.G. Maksimov  I.I. Mazin
Affiliation:P.N. Lebedev Physical Institute, B-333, Moscow, USSR
Abstract:Lorentz-Lorenz formula may be derived microscopically by the analytical inversion of the dielectric matrix (DM) in the limit of tightly bound electrons. Exchange and correlation effects are to be taken into account and atomic polarisability is to be defined correctly in terms of the atomic susceptibility instead of the polarization operator. A wrong definition was the origin of usual contradictions between microscopical calculations and classical formula. The inversion of the DM diminishes dielectric constant in comparison with the diagonal element of DM but this procedure takes into account only a part of the local field effects caused by rapidly oscillating fields. Another part is connected with exchange interaction and increases the diagonal element of DM in comparison with dielectric constant without any local field effects, hence all local field effects do increase the dielectric constant.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号