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Chain-terminus triggered chiral memory in an optically inactive 3(10)-helical peptide
Authors:Ousaka Naoki  Inai Yoshihito  Kuroda Reiko
Affiliation:Japan Science and Technology Agency, ERATO-SORST Kuroda Chiromorphology Team, 4-7-6, Komaba, Meguro-ku, Tokyo 153-0041, Japan.
Abstract:A new optically inactive 3(10)-helical peptide with a side-chain cross-linking was found to exhibit chiral memory stored in the peptide backbone, whose chirality was induced by a noncovalent interaction of a chiral molecule at the N-terminal end of the peptide.
Keywords:
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