| 丹酰基丝氨酸与桥联双环糊精作用机理的时间分辨荧光光谱研究 |
| |
| 引用本文： | 陈凯,贾树岩,郝雅琼,吴立新,吴玉清,刘俊秋,刘瑞斌,张建平,艾希成.丹酰基丝氨酸与桥联双环糊精作用机理的时间分辨荧光光谱研究[J].高等学校化学学报,2005,26(4):693-696. |
| |
| 作者姓名： | 陈凯 贾树岩 郝雅琼 吴立新 吴玉清 刘俊秋 刘瑞斌 张建平 艾希成 |
| |
| 作者单位： | 1. 吉林大学超分子结构和材料教育部重点实验室, 长春 130012;
2. 分子动态和稳态结构国家重点实验室, 中国科学院化学研究所分子科学中心, 北京 100080 |
| |
| 基金项目： | 中国科学院资助项目;国家重点基础研究发展计划(973计划) |
| |
| 摘 要： | 利用稳态、时间分辨荧光光谱,结合非线性最小二乘法拟合系统研究了手性探针分子丹酰-L-丝氨酸(DLS)与β-环糊精(β-CD)、2-位硒桥联β-CD(1)和2-位碲桥联β-CD(2)的复合及复合机理.对比研究了DLS与三种不同环糊精复合强度及复合方式的差别.结果表明,引入硒桥键不能使化合物1与丹酰基丝氨酸分子很好地复合;而引入碲桥键使化合物2对DLS分子的结合能力相对于β-CD有明显增强.
|
| 关 键 词： | 丹酰基丝氨酸 硒桥联双环糊精 碲桥联双环糊精 非线性最小二乘法拟合 时间分辨荧光光谱 |
| 文章编号： | 0251-0790(2005)04-0693-04 |
| 收稿时间： | 2004-09-14 |
Time-resolved Fluorescence Spectroscopic Studies on Interaction Mechanism of Dansyl-L-serine with Bridged-bicyclodextrins |
| |
| CHEN Kai,JIA Shu-Yan,HAO Ya-Qiong,WU Li-Xin,WU Yu-Qing,LIU Jun-Qiu,LIU Rui-Bin,ZHANG Jian-Ping,AI Xi-Cheng.Time-resolved Fluorescence Spectroscopic Studies on Interaction Mechanism of Dansyl-L-serine with Bridged-bicyclodextrins[J].Chemical Research In Chinese Universities,2005,26(4):693-696. |
| |
| Authors: | CHEN Kai JIA Shu-Yan HAO Ya-Qiong WU Li-Xin WU Yu-Qing LIU Jun-Qiu LIU Rui-Bin ZHANG Jian-Ping AI Xi-Cheng |
| |
| Institution: | 1. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130012, China;
2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China |
| |
| Abstract: | Time-resolved fluorescence spectra were applied to study the binding of dansyl-L-serine(DLS) with β-cyclodextrin(β-CD), 2-selenium bridged β-cyclodextrin(1) and 2-tellurium bridged β-cyclodextrin(2). The differentiations of DLS in binding with three kinds of cyclodextrins were performed. The results suggest that compound 1 cannot bind with DLS efficiently. However, compound 2 can enhance the binding ability with DLS greatly in comparison with that of β-CD. |
| |
| Keywords: | Dansyl-L-serine 2-Selenium bridged β-cyclodextrin 2-Tellurium bridged β-cyclodextrin Non-linear least-square curve fitting Time-resolved fluorescence spectroscopy |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
