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Novel oligo-m-carboranylenemethylenesilanes |
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| Authors: | Izmaylov B A Vasnev V A Markova G D |
| Institution: | 1.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation ; |
| Abstract: | A method has been developed for the obtaining of new oligo(dimethyl)silanes comprising 1,7-bis(methyl)-m-carboranyl units and bearing the terminal chlorosilyl or methoxysilyl groups. Reactions of such oligomers with an excess of benzylmagnesium chloride or 1-chloromagnesiummethyl-m-carborane lead to oligo-m-carboranylenemethylenesilanes containing the terminal benzylsilyl or m-carboranylmethylenesilyl groups. The novel oligomers are highly viscous liquids possessing a high heat resistance and also a resistance towards the treatment with a strong alkaline reagent. |
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