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Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
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| Authors: | Ismiyev A I Dotsenko V V Aksenov N A Aksenova I V Magerramov A M |
| Institution: | 1.Baku State University, 23 Z. Khalilov str., AZ1148, Baku, Azerbaijan ;2.Kuban State University, 149 Stavropolskaya ul., 350040, Krasnodar, Russian Federation ;3.North-Caucasus Federal University, 1a ul. Pushkina, 355009, Stavropol, Russian Federation ; |
| Abstract: | The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction. |
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