Co(II)5(OH)6(SO4)2(H2O)4: the first ferromagnet based on a layered cobalt-hydroxide pillared by inorganic...OSO3-Co(H2O)4-O3SO.. |
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| Authors: | Ben Salah Mohsen Vilminot Serge Richard-Plouet Mireille André Gilles Mhiri Tahar Kurmoo Mohamedally |
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| Institution: | Groupe des Matériaux Inorganiques, IPCMS, CNRS-ULP UMR 7504, Strasbourg, France. |
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| Abstract: | The synthetic mineral Co(II)5(OH)6(SO4)2(H2O)4 (1), obtained by hydrothermal reaction of CoSO4.7H2O and NaOH at 165 degrees C and consisting of brucite-like Co4(OH)6O2 layers pillared by OSO3-Co(H2O)4-O3SO, is a ferromagnet (T(Curie)= 12 K, Hc= 580 Oe). |
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