| 可修饰的内酯，α-氯甲基-α-甲基-β-丙内酯的合成和聚合 |
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| 引用本文： | 王明霞 李子臣. 可修饰的内酯，α-氯甲基-α-甲基-β-丙内酯的合成和聚合[J]. 高分子学报, 1996, 0(6): 736-739 |
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| 作者姓名： | 王明霞 李子臣 |
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| 作者单位： | 北京大学化学系 |
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| 摘 要： | 可修饰的内酯，α－氯甲基－α－甲基－β－丙内酯的合成和聚合＊王明霞李子臣贺晓晖杨丽＊＊李福绵（北京大学化学系北京１００８７１）关键词α－氯甲基－α－甲基－β－丙内酯，开环聚合＊１９９５－０２－２０收稿；１９９６－０３－１２修回：自然科学基金课题；＊＊...
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| 关 键 词： | α-氯甲基-α-甲基-β-丙内酯，开环聚合 |
SYNTHESIS AND RING OPENING POLYMERIZATION OF MODIFIABLE LACTONE,α CHLOROMETHYL α METHYL β PROPIOLACTONE |
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| WANG Mingxia,LI Zichen,HE Xiaohui,YANG Li,LI Fumian. SYNTHESIS AND RING OPENING POLYMERIZATION OF MODIFIABLE LACTONE,α CHLOROMETHYL α METHYL β PROPIOLACTONE[J]. Acta Polymerica Sinica, 1996, 0(6): 736-739 |
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| Authors: | WANG Mingxia LI Zichen HE Xiaohui YANG Li LI Fumian |
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| Abstract: | ? Chlormethyl α methyl β propiolactone(CMMPL)was synthesized by dehydrochlorination of dichloromethyl propionic acid(DCMPA)in the presence of DOH.The ring opening polymerization of CMMPL was successfully carried out by using Sn(Oct) 2,Ti(OBu) 4,Al(i OPr) 4 and Al(Et) 3 as initeators in bulk or solution.Powder X ray diffraction and DSC measurement showed that P(CMMPL) was a kind of high crystalline polymer. Both the polymerization conversion and the properties of the polymer were affected by the monomer concentreation and the polymerization time. |
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| Keywords: | ? Chloromethyl α methyl β propiolactone Ring opening polymerizationPPAGEESS |
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