| 微波条件下固体酸催化合成己二酸酯 |
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| 引用本文： | 李楠,樊兴君,苑克国,谭干祖.微波条件下固体酸催化合成己二酸酯[J].五邑大学学报(自然科学版),2001,15(1):15-17. |
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| 作者姓名： | 李楠 樊兴君 苑克国 谭干祖 |
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| 作者单位： | 1. 五邑大学化学与环境工程系,
2. 中国科学院兰州化学物理研究所, |
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| 摘 要： | 采用微波辐射技术，以活性炭、木炭担载的对甲苯磺酸为催化剂，常压下己二酸和醇直接酯化合成己二酸酯类，酸醇物质的量的比为14，对甲苯磺酸浓度为26％，催化剂用量0.8g，反应时间45s，转化率较高，且催化剂可重复使用.
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| 关 键 词： | 微波辐射 固体酸 酯化 |
| 文章编号： | 1006-7302(2001)01-0015-03 |
| 修稿时间： | 2000年4月28日 |
Synthesis of adipates by Catalysis of Solid Acid under Microwave Irradiation |
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| LI Nan,FAN Xing-jun,YUAN Ke-guo,TAN Gan-zu.Synthesis of adipates by Catalysis of Solid Acid under Microwave Irradiation[J].Journal of Wuyi University(Natural Science Edition),2001,15(1):15-17. |
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| Authors: | LI Nan FAN Xing-jun YUAN Ke-guo TAN Gan-zu |
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| Institution: | LI Nan1,FAN Xing-jun2,YUAN Ke-guo2,TAN Gan-zu2 |
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| Abstract: | The synthesis of adipates were performed by esterification of adipic acid and alcohol incatalysis of p-toluenesulfonic acid loaded on active carbon or charcoal under microwave irradiation.The optimal reaction conditions were as follows: the mole ratio ofadipic acid to alcohol was 1: 4;the concentration of p-toluenesulphonic acid solution was 25%; the weights of catalyst, microwavepower, and microwave irradiation time were 0.8 g, 600 W, and 45 s respectively. The conversionratio of adipic acid in these reactions was high moreover the catalyst can be easily separated andused repeatedly. |
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| Keywords: | microwave irradiation solidacid catalyst esterification |
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