| 基于2,3,5,6-四氟对苯二甲酸构筑的两个超分子网络结构的合成、结构和荧光性质(英文) |
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| 引用本文： | 冉行蕊,谢卫萍,熊艳菊,程谦,乐善堂,刘应亮. 基于2,3,5,6-四氟对苯二甲酸构筑的两个超分子网络结构的合成、结构和荧光性质(英文)[J]. 无机化学学报, 2014, 30(11): 2662-2668 |
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| 作者姓名： | 冉行蕊 谢卫萍 熊艳菊 程谦 乐善堂 刘应亮 |
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| 作者单位： | 华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;广州市能源转换和存储材料重点实验室, 广州 510006;华南农业大学理学院应用化学系, 广州 510642 |
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| 基金项目： | 国家自然基金(No.20971047,U0734005,21271076),广东省教育厅重点项目(No.cxzd1020),广州市科技计划项目(No.2013J4100049)。 |
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| 摘 要： | 在水热条件下合成了基于四氟对苯二甲酸的2个二维微孔配位聚合物{[Cd2(IP)2(tfBDC)2(H2O)2]·H2O}n(1)和{[Mn2(IP)2(tfBDC)2(H2O)2]·H2O}n(2)(tfBDC=2,3,5,6-四氟对苯二甲酸,IP=1-H-咪唑[4,5-f][1,10]-菲咯啉)。二维层状结构是44-网状结构,三维超分子结构是由氢键连接相邻的二维层状结构而形成的。2个配位聚合物均用元素分析、热重分析(TGA)、粉末衍射(PXRD)、红外光谱(FT-IR)进行了表征,且对配合物1的荧光性质进行了详细的分析。
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| 关 键 词： | 配位聚合物 超分子网状结构 水热合成 荧光性质 |
| 收稿时间： | 2014-07-08 |
| 修稿时间： | 2014-07-30 |
Syntheses, Structures, and Fluorescence of Two Supramolecular Networks Based on 2,3,5,6-Tetrafluoroterephthalate |
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| RAN Xing-Rui,XIE Wei-Ping,XIONG Yan-Ju,CHENG Qian,YUE Shan-Tang and LIU Ying-Liang. Syntheses, Structures, and Fluorescence of Two Supramolecular Networks Based on 2,3,5,6-Tetrafluoroterephthalate[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(11): 2662-2668 |
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| Authors: | RAN Xing-Rui XIE Wei-Ping XIONG Yan-Ju CHENG Qian YUE Shan-Tang LIU Ying-Liang |
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| Affiliation: | School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou 510006, China;College of Science, South China Agricultural University, Guangzhou 510642, China |
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| Abstract: | Two isomorphous 2D coordination polymers {[Cd2(IP)2(tfBDC)2(H2O)2]·H2O}n (1) and {[Mn2(IP)2(tfBDC)2(H2O)2]·H2O}n (2) [tfBDC=2,3,5,6-tetrafluoroterephthalic acid, IP=1-H-imidazo[4,5-f][1,10]-phenanthroline], based on tetrafluoroterephthalate, have been successfully synthesized under hydrothermal conditions. The 2D layer is 44-network. In addition, the neighboring 2D sheets are connected by hydrogen bonds into 3D supramolecular architecture. Both the complexes are characterized by elemental analyses, thermogravimetric analyses (TGA), powder X-ray diffraction patterns (PXRD), FT-IR spectroscopy. Furthermore, the luminescence property of complex 1 was also investigated in detail. CCDC: 995988, 1; 995989, 2. |
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| Keywords: | coordination polymer supramolecular networks hydrothermal synthesis luminescent properties |
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