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Oxidation of secondary amines by molecular oxygen and cyclohexanone monooxygenase |
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| Authors: | Stefano Colonna Vincenza Pironti Piero Pasta |
| Affiliation: | a Istituto di Chimica Organica, ‘Alessandro Marchesini’, Facoltà di Farmacia, via Venezian 21, 20133 Milano, Italy b Istituto di Chimica del Riconoscimento Molecolare, CNR, via Mario Bianco 9, 20131 Milano, Italy |
| Abstract: | Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzed the oxidation of tertiary and secondary amines to N-oxides and nitrones, respectively. The formation of a hydroxylamine intermediate was involved with secondary amines as starting substrates. |
| Keywords: | Cyclohexanone monooxygenase Nitrones Amines Hydroxylamines N-Oxides |
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