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Stereochemistry of the [2+4] cycloaddition of cyclopentyne |
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| Authors: | John C. Gilbert Duen-Ren Hou |
| Affiliation: | a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station Stop A5300, Austin, TX 78712, USA b Department of Chemistry, National Central University. No. 300, Jung-Da Road, Jung-Li City, Taoyuan 320, Taiwan, ROC |
| Abstract: | The [2+4] cycloaddition of cyclopentyne with a pair of diastereomeric 1,3-dienes is found to occur with high stereoselectivity. The results support the applicability of the principles of orbital symmetry even in the case of this exceedingly reactive dienophile. |
| Keywords: | Cyclopentyne Diels-Alder Reaction Stereochemistry Orbital symmetry |
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