In situ X-ray analysis of solid/electrolyte interfaces: electrodeposition of Cu and Co on Si(1 1 1):H and GaAs(0 0 1) and corrosion of Cu3Au(1 1 1) |
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Authors: | J. Zegenhagen F.U. Renner T.L. Lee A. Stierle G. Scherb D.M. Kolb |
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Affiliation: | a European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble Cedex, France b Abteilung Elektrochemie, Universität Ulm, D-89069 Ulm, Germany c Max-Planck-Institut für Metallforschung, D-70569 Stuttgart, Germany d Max-Planck-Institut für Festkörperforschung, D-70569 Stuttgart, Germany e Norwegian University of Science and Technology, NO-7491 Trondheim, Norway |
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Abstract: | Electrochemical deposition of Cu and Co in monolayer amounts on hydrogen terminated Si(1 1 1) was studied ex situ and in situ by X-ray techniques. The X-ray beam was found to have a strong effect on the deposit causing desorption under the beam. Cu deposition on GaAs(0 0 1) from UHV is compared with electrodeposited Cu on the same surface, elucidating similarities and differences of electrochemical and UHV deposition. Roughening due to corrosion of Cu3Au(1 1 1) is observed by crystal truncation scattering. The observed behaviour of passivation of this surface is explained by the formation of Au clusters, increasingly covering the surface at higher oxidation potential. |
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Keywords: | Electrochemical methods X-ray standing waves X-ray scattering, diffraction, and reflection Epitaxy Copper Gold Cobalt Silicon Single crystal surfaces Solid-liquid interfaces Clusters |
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