Reaction pathways of zirconocene-catalyzed silylation of alkenes with chlorosilanes |
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| Authors: | Jun Terao |
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| Affiliation: | Department of Molecular Chemistry and Science and Technology Center for Atoms, Molecules and Ions Control, Osaka University, Suita, Osaka 565-0871, Japan |
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| Abstract: | Reaction pathways as well as stereochemistries and stoichiometries of zirconocene-catalyzed silylation of olefins with chlorosilanes in the presence of nBuMgCl were studied and discussed in detail. Rate determining steps were examined by kinetic studies and labeling experiments. |
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| Keywords: | Zirconocene Silylation Chlorosilanes Olefins Grignard reagents |
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