|
|||||
|
|
Cyclo- and carbomagnesiation of 1,2-dienes catalyzed by Zr complexes |
|
| Authors: | Usein M Dzhemilev Vladimir A D'yakonov Leila O Khafizova Askhat G Ibragimov |
| Institution: | Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences, and Ufa Scientific Centre of Russian Academy of Sciences, 141 Prospekt Oktyabrya, Ufa 450075, Russian Federation |
| Abstract: | Cyclo- and carbomagnesiation of 1,2-dienes with EtMgR′ (R′=Et, Br) in the presence of Cp2ZrCl2 catalyst lead to alkylidenemagnesiocyclopentanes. Deuterolysis provides insights into the reaction pathways. |
| Keywords: | Catalysis Zr complexes Organomagnesium compounds Cyclomagnesiation Carbomagnesiation 1 2-Dienes Deuterolysis |
| 本文献已被 ScienceDirect 等数据库收录！ | |