Abstract: | The contributions of entropy and elastic forces to the tensile modulus of a polymer chain are estimated. The chain length-distribution function in the amorphous region of highly oriented Lavsan is approximately determined from macroscopic stress-strain dependence. It is found that the length distribution has a width of the order of several percent of the length of the amorphous region of the fibril.A. F. Ioffe Physicotechnical Institute, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 922–925, September–October, 1974. |