Heterogeneous catalytic synthesis and structure of 5,5a,10a,11-tetrahydro-10H-indeno[1,2-b]quinoline期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Heterogeneous catalytic synthesis and structure of 5,5a,10a,11-tetrahydro-10H-indeno[1,2-b]quinoline

Authors:	Pleshakov V. G. Ambacheu K. D. Ryashentseva M. A. Sergeeva N. D. Vener M. V. Murugova L. A. Zvolinsky O. V. Prostakov N. S.

Affiliation:	(1) Russian People's Friendship University, 6 ul. Miklucho-Maklaya, 117198 Moscow, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation

Abstract:	Hydrogenation of 10H-indeno[1,2-b]quinoline in benzene in the presence of R₂S₇ $(250 ^circ C, p_{H_2 } = 140 atm, 4 h)$ gave 5,5a,10a,11-tetrahydro-10H-indeno[1,2-b]quinoline, the structure of which was established by mass-, IR, UV,¹³C, and¹H NMR spectra. Thecis fusion of the indan and tetrahydroquinoline fragments, the axial orientation of the proton at C(5a), and the equatorial orientation of the proton at C(10a) were confirmed by molecular mechanics calculations using the PC MODEL program.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1098–1101, June, 1994.

Keywords:	10H-indeno[1,2-b]quinoline, hydrogenation rhenium heptasulfide 5,5a,10a,11-tetrahydro-10H-indeno[1,2-b]quinoline, stereochemistry molecular mechanics calculations, PC MODEL program
本文献已被 SpringerLink 等数据库收录！