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The role of intrachain dipole interactions in the formation of the supramolecular structure of crystallizing ferroelectric polymers |
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| Authors: | V. V. Kochervinskiĭ V. V. Volkov K. A. Dembo |
| Affiliation: | (1) State Scientific Center “Troitsk Institute for Innovation and Thermonuclear Research”, Troitsk, Moscow oblast, 142190, Russia;(2) Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia |
| Abstract: | The role of intrachain dipole interactions in the formation of a lamellar morphology is investigated using a number of statistical vinylidene fluoride copolymers with nonpolar components as an example. It is shown that the large and interlamellar spacings regularly increase as the intrachain dipole interaction weakens. |
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