Formal synthesis of ent-dysiherbaine from sulfinyl dihydropyrans by sigmatropic rearrangement and tethered aminohydroxylation |
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| Authors: | Roberto Ferná ndez de la Pradilla,Nadia Lwoff,Alma Viso |
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| Affiliation: | Instituto de Química Orgánica, CSIC, Juan de la Cierva, 3, 28006 Madrid, Spain |
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| Abstract: | A stereospecific [2,3]-sigmatropic rearrangement of a sulfinyl dihydropyran, followed by a tethered aminohydroxylation reaction, are the key steps of a formal synthesis of ent-dysiherbaine from an enantiopure sulfinyl dienol. |
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| Keywords: | Allylic sulfoxides Sigmatropic rearrangement Tethered aminohydroxylation |
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