Thermodynamic stability of neodymium nitrate complex with 1,10-phenanthroline |
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| Authors: | A. S. Alikhanyan I. A. Solonina M. N. Rodnikova |
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| Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | The thermodynamic stability of neodymium nitrate complex with 1,10-phenanthroline (Phen) was determined by mass spectrometry. The complex was formulated as Nd(NO3)3 · 2C12H8N2 on the basis of elemental analysis. Mass spectrometry allowed us to characterize the decomposition of Nd(NO3)3 · 2C12H8N2 thermodynamically. The formation enthalpy of this complex is ?1058.0 kJ/mol. |
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