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A novel stereoselective synthesis of (E)-2-arylvinylphosphonates in InCl3-NaBH4-MeCN system |
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| Authors: | Chunyan Wang Deyu Yang |
| Institution: | Department of Chemistry, Zhejiang University (Yuquan campus), Hangzhou 310027, PR China |
| Abstract: | Hydroindation of arylalkynylphosphonates gives a intermediate which can be hydrolyzed to (E)-2-arylvinylphosphonates in InCl3-NaBH4-MeCN system, the stereoselectivity and yield are rather high, but under the same conditions 2-alkylalkynylphosphonates do not react very well. |
| Keywords: | InCl3-NaBH4-MeCN system Hydroindation (E)-2-Arylvinylphosphonates Stereoselectivity Alkynylphosphonates |
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