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Cross-coupling of vinyldisilacyclobutane with olefins catalyzed by [RuH(Cl)(CO)(PCy3)2] |
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| Authors: | Magdalena Jankowska Natalia Bespalova Bogdan Marciniec |
| Institution: | a Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland b Topchiev Institute of Petrochemical Synthesis, Leninsky pr., 29, 119333 Moscow, Russian Federation |
| Abstract: | Cross-coupling of vinyldisilacyclobutane with a variety of olefins in the presence of RuH(Cl)(CO)(PCy3)2] leads to stereoselective formation of functionalized vinyldisilacyclobutanes. Analogous homo-coupling of vinyldisilacyclobutane leads to the formation of E- and gem-bis(silyl)ethenes. The reaction offers a new route for synthesis of attractive monomers for ring opening polymerization (ROP). |
| Keywords: | Silylative coupling Ruthenium complex Vinyldisilacyclobutane Disilacyclobutane derivatives |
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