One-pot synthesis of the new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs]; preparation and structures of two rhodium derivatives |
| |
Authors: | Luigi Busetto M. Cristina Cassani Vincenzo G. Albano |
| |
Affiliation: | a Dipartimento di Chimica Fisica ed Inorganica, viale Risorgimento 4, I-40136 Bologna, Italy b Dipartimento di Chimica “G. Ciamician”, via Selmi 2, I-40126 Bologna, Italy |
| |
Abstract: | The new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes [Rh{η5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and [Rh{η5-C5H4CO2 (CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures. |
| |
Keywords: | Cyclopentadienyl ligands Oxazolidin-2-ones Rhodium complexes X-ray diffraction |
本文献已被 ScienceDirect 等数据库收录! |