One-pot synthesis of the new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs]; preparation and structures of two rhodium derivatives |
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| Authors: | Luigi Busetto M Cristina Cassani Vincenzo G Albano |
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| Institution: | a Dipartimento di Chimica Fisica ed Inorganica, viale Risorgimento 4, I-40136 Bologna, Italy
b Dipartimento di Chimica “G. Ciamician”, via Selmi 2, I-40126 Bologna, Italy |
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| Abstract: | The new dianionic ligand Na]2C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes Rh{η5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and Rh{η5-C5H4CO2 (CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures. |
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| Keywords: | Cyclopentadienyl ligands Oxazolidin-2-ones Rhodium complexes X-ray diffraction |
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