The Heck-type arylation of allylic alcohols with arenediazonium salts |
| |
| Authors: | Judit Masllorens Sandrine Bouquillon Françoise Hénin |
| |
| Institution: | a Department of Chemistry, Universitat de Girona, Campus de Montilivi, 17071 Girona, Spain
b Unité Mixte de Recherche “Réactions Sélectives et Applications”, CNRS - Université de Reims Champagne-Ardenne, B.P. 1039, 51687 Reims Cedex 2, France |
| |
| Abstract: | The Heck coupling of ArN2BF4 with secondary allylic alcohols, carried out in methanol using Pd(dba)2 as catalyst without extra ligands and base, leads to the corresponding β-arylated carbonyl compounds. Such conditions afford arylated acetals from primary allylic alcohols. |
| |
| Keywords: | Arylation Palladium Allylic alcohols Ketones Acetals Arenediazonium salts |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
