Desymmetrisation of a diallyl system by intramolecular Heck reaction |
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| Authors: | Michael P Coogan Mark J Pottenger |
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| Institution: | Department of Chemistry, Cardiff University, Park Place, Cardiff CF10 3TB, Cymru/Wales, UK |
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| Abstract: | The development of a desymmetrising cyclisation of a benzylic diallyl iodide is reported. The final procedure generates a new quaternary chiral centre in greater than 80% yield giving a highly functionalised methylene indan product suitable for further application in synthesis. |
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| Keywords: | Heck reaction Desymmetrisation |
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