Development of novel and efficient synthesis of group 14 element (Ge and Sn) catenates by use of samarium (II) diiodide |
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| Authors: | Takushi Azemi Kunio Mochida |
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| Affiliation: | Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan |
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| Abstract: | Group 14 element catenates such as di-, tri-, poly-germanes, and polystannanes are efficiently synthesized by use of the one-electron reducing agent SmI2 under mild homogeneous conditions in good yields. |
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| Keywords: | Group 14 elements Catenates Samarium (II) diiodide |
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