[Me8Pt4ReS4] and related PtMe2-containing clusters derived from tetrathiorhenate |
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| Authors: | Haijun Yao Scott R. Wilson |
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| Affiliation: | Department of Chemistry, University of Illinois at Urbana-Champaign, 601 s. Goodwin, Urbana, IL 61801, USA |
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| Abstract: | The reactions of Pt2Me4(μ-SMe2)2 and [ReS4]− in MeCN solution have been investigated. The resulting polyalkylated clusters: Et4N[ReS4PtMe2] (Et4N[1]), Et4N[ReS4(PtMe2)2] (Et4N[2]), and Et4N[ReS4(PtMe2)4] (Et4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms. |
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| Keywords: | Cluster Sulfide Rhenium Platinum |
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