Synthesis of zirconocenes bearing benz[f]indenyl ligand and their use as a catalyst in ethylene polymerization |
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| Authors: | Do Han Kim Bun Yeoul Lee |
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| Affiliation: | a Department of Chemistry, Seoul National University, Seoul 151-747 N60, Korea
b Department of Molecular Science and Technology, Ajou University, Suwon 442-749, Korea |
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| Abstract: | Benz[f]indenyl zirconium complexes have been successfully synthesized and characterized. Their catalytic activities were evaluated for the polymerization of ethylene. The complexes combined with MAO can be highly active single site catalysts, which display activities comparable with that of the Cp2ZrCl2/MAO system and provide very high molecular weight polyethylenes. The melting point of the polymers indicates the formation of linear polyethylene. |
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| Keywords: | Benz[f]indenyl Zirconium Cyclopentadienyl Ethene Polymerization |
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