Fluoroaryl-substituted ketiminate complexes of aluminum |
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| Authors: | Piyush Shukla Alan H Cowley Jamie N Jones |
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| Institution: | a Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, 1 University Station A5300, Austin, TX 78712, USA
b Los Alamos National Laboratory, Chemistry Division, MS J514, Los Alamos, NM 87545, USA |
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| Abstract: | The ketiminate complex AlClOC(Me)CHC(Me)N(p-C6H4F)]2 (4) has been prepared from the β-aminoenone, O C(Me)CHC(Me)N(H)(p-C6H4F) (3) by lithiation of 3 with n-BuLi, followed by reaction with AlCl3 and by the reaction of 3 with Me2AlCl. A second compound, AlCl2{OC(Me)CHC(Me)N(H)(p-C6H4F)}4]AlCl4] (5), was also isolated from the AlCl3 reaction. The structures of 4 and 5 were determined by X-ray diffraction analysis. |
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| Keywords: | Ketiminate β-Aminoenone Aluminum Complexes Syntheses Structures |
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