| 稳态荧光探针法研究二聚壬基酚聚氧乙烯醚硫酸钠的表面行为 |
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| 引用本文： | 张彬,黎钢,杨芳,徐念,刘荣,刘洋. 稳态荧光探针法研究二聚壬基酚聚氧乙烯醚硫酸钠的表面行为[J]. 影像科学与光化学, 2009, 27(4): 296-301. DOI: 10.7517/j.issn.1674-0475.2009.04.296 |
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| 作者姓名： | 张彬 黎钢 杨芳 徐念 刘荣 刘洋 |
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| 作者单位： | 河北工业大学,化工学院,天津300130;河北工业大学,化工学院,天津300130;河北工业大学,化工学院,天津300130;河北工业大学,化工学院,天津300130;河北工业大学,化工学院,天津300130;河北工业大学,化工学院,天津300130 |
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| 摘 要： | 介绍了以二聚壬基酚聚氧乙烯醚,氨基磺酸,氢氧化钠为原料,合成二聚壬基酚聚氧乙烯醚硫酸钠(GNPES),同样方法合成壬基酚聚氧乙烯醚硫酸钠(NPES),以芘为荧光探针,用稳态荧光探针法测定了合成的GNPES和NPES的临界胶束浓度。
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| 关 键 词： | 稳态荧光猝灭 临界胶束浓度 二聚壬基酚聚氧乙烯醚硫酸钠 |
| 收稿时间： | 2008-11-25 |
The Study of Surface Activity Properties of Gemini Sodium Nonylphenol Polyoxyethylene Ether Sulfate by Steady-State Fluorescence |
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| ZHANG Bin,LI Gang,YANG Fang,XU Nian,LIU Rong,LIU Yang. The Study of Surface Activity Properties of Gemini Sodium Nonylphenol Polyoxyethylene Ether Sulfate by Steady-State Fluorescence[J]. Imaging Science and Photochemistry, 2009, 27(4): 296-301. DOI: 10.7517/j.issn.1674-0475.2009.04.296 |
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| Authors: | ZHANG Bin LI Gang YANG Fang XU Nian LIU Rong LIU Yang |
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| Affiliation: | School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130 |
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| Abstract: | A novel gemini sodium nonylphenol polyoxyethylene ether sulfate(GNPES) were synthesized by gemini nonylphenol polyoxyethylene ether,sulfamic acid and 30%aqueous sodium hydroxide. Sodium nonylphenol polyoxyethylene ether sulfate(NPES) were synthesized with the same method.Critical micelle concentration(CMC) of GNPES and NPES were determined by steadystate fluorescence probe method in which pyrene was used as fluorescence probe.The experimental results showed that the CMC of GNPES was more less than that of NPES while the capability of reducing surface tension of the GNPES was almost the same as that of NPES. |
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| Keywords: | steady-state fluorescence quenching critical micelle concentration gemini sodium nonylphenol polyoxyethylene ether sulfate |
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