|
|||||
|
|
A Gallium‐Substituted Distibene and an Antimony‐Analogue Bicyclo[1.1.0]butane: Synthesis and Solid‐State Structures |
|
| Authors: | M?Sc Lars Tuscher Dr Chelladurai Ganesamoorthy Dieter Bläser Dr Christoph Wölper Prof?Dr Stephan Schulz |
| Institution: | Faculty of Chemistry, University of Duisburg–Essen, Universit?tsstrasse 5–7, S07 S03 C30, 45117 Essen (Germany) |
| Abstract: | RGa {R=HCC(Me)N(2,6‐iPr2C6H3)]2} reacts with Sb(NMe2)3 with insertion into the Sb? N bond and elimination of RGa(NMe2)2 ( 2 ), yielding the Ga‐substituted distibene R(Me2N)GaSb?SbGa(NMe2)R ( 1 ). Thermolysis of 1 proceeded with elimination of RGa and 2 and subsequent formation of the bicyclo1.1.0]butane analogue R(Me2N)Ga]2Sb4 ( 3 ). |
| Keywords: | Group 13 elements main‐group elements metal– metal interactions multiple bonding |