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Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]−
Authors:Qingnan Zhang  Wan‐Lu Li  Cong‐Qiao Xu  Dr. Mohua Chen  Prof. Mingfei Zhou  Prof. Jun Li  Dr. Diego M. Andrada  Prof. Gernot Frenking
Affiliation:1. Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433 (China);2. Department of Chemistry & Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084 (China);3. Fachbereich Chemie, Philipps‐Universit?t Marburg, Hans‐Meerwein‐Strasse, 35043 Marburg (Germany);4. Donostia International Physics Center (DIPC), P.K. 1072, 20080 Donostia (Spain)
Abstract:We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]?. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]? using state‐of‐the‐art quantum chemical methods.
Keywords:bonding analysis  boron dicarbonyl compound  matrix isolation  quantum chemical calculations
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