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Attenuated Organomagnesium Activation of White Phosphorus |
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| Authors: | Dr. Merle Arrowsmith Prof. Michael S. Hill Dr. Andrew L. Johnson Dr. Gabriele Kociok‐Köhn Dr. Mary F. Mahon |
| Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK) |
| Abstract: | Sequential reactions between a 2,6‐diisopropylphenyl‐substituted β‐diketiminato magnesium n‐butyl derivative and P4 allow the highly discriminating synthesis of unusual [nBu2P4]2? and [nBu2P8]2? cluster dianions. |
| Keywords: | cluster compounds magnesium P4 activation phosphorus structure elucidation |