MORPHOLOGICAL STUDIES OF A THERMOTROPIC SIDE-CHAIN LIQUID CRYSTALLINE POLYMER DURING MESOPHASE TRANSITIONS* |
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Authors: | Chi-bing Tan Quan-ling Zhang Shu-fan Zhang Xia-yu Wang Mao Xu |
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Affiliation: | Polymer Physics Laboratory; Institute of Chemistry; Chinese Academy of Sciences; Beijing 100080; China |
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Abstract: | The morphological features of a side-chain liquid crystalline polymer during the mesophasetransitions were investigated by using the DSC technique. The polymer used was polyacrylate with mesogensof three benzene rings attached to the main chain through a flexible spacer. A special two-phase texture wasobserved in the transition temperature range. Similar to main-chain liquid crystalline polymers the transitionprocess of the side-chain liquid crystalline polymer was composed of an initiation of the new phase at localplaces of the old phase matrix and a growth process of the new phase domains. |
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Keywords: | Side-chain liquid crystalline polymer Mesophase transition Polarizing microscopy |
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