Triangular and tetrahedral array of silver(I) ions by a novel disk-shaped tridentate ligand: dynamic control of coordination equilibrium of the silver(I) complexes |
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| Authors: | Hiraoka Shuichi Yi Tao Shiro Motoo Shionoya Mitsuhiko |
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| Institution: | Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. |
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| Abstract: | A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal-ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution. |
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