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Use of high-voltage electroaccumulation for lowering the detection limit for silver in stripping voltammetry
Authors:L I Skvortsova  V N Kiryushov
Institution:(1) Institute of Solid-State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, 630128 Novosibirsk, Russia
Abstract:The use of high-voltage electroaccumulation in the determination of silver by stripping voltammetry at a mechanically renewed graphite electrode with an area of 2.5 × 10−3 cm2 in 0.2% boric acid acidified with acetic acid at a voltage of 400 V and at an accumulation time of 5 min lowered the detection limit for silver to 1 × 10−12 M.
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