High-nuclearity 3d-4f [FeIII5LnIII8] complexes: synthesis, structure and magnetic properties |
| |
| Authors: | Ako Ayuk M Mereacre Valeriu Clérac Rodolphe Hewitt Ian J Lan Yanhua Anson Christopher E Powell Annie K |
| |
| Institution: | Institut für Anorganische Chemie der Universit?t Karlsruhe, Karlsruhe, German. |
| |
| Abstract: | The isostructural tridecanuclear mixed-metal FeIII5LnIII8] (Ln = Pr, Nd, Gd) aggregates are the largest Fe-Ln] clusters reported to date and the magnetic properties suggest a ferrimagnetic arrangement in Fe5Pr8] and Fe5Nd8], whereas for Fe5Gd8] ferromagnetic interactions are dominant leading to a large spin ground state. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
