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KDP晶体的太赫兹光谱研究
引用本文:崔德勇,张晓霞,熊煜,钱铄. KDP晶体的太赫兹光谱研究[J]. 光学与光电技术, 2012, 0(1): 84-87
作者姓名:崔德勇  张晓霞  熊煜  钱铄
作者单位:电子科技大学光电信息学院
基金项目:国家高科技研究发展计划(863计划)新材料领域(2009AA03Z413)资助项目
摘    要:实验测量了室温下磷酸二氢钾(KDP)晶体0.2~1.6THz的时域光谱,以及50~4000cm叫范围内的远红外光谱,200~2000nm的紫外一可见一红外光谱。KDP晶体的禁带宽度是5.91eV,在测量范围内有一个很宽的声子吸收带,从0.2~205.5THz吸收系数在35~80cm-1,声子吸收的低频端小于0.2THz。最高的纵光学模声子的频率大约是205.5THz,由此求出这支声子的H—O键的力常数为13.13N·cm-1。

关 键 词:THz光谱  红外一紫外光谱  KH2PO4  晶体  声子吸收

THz Spectra of KDP Crystal
CUI De-yong,ZHANG Xiao-xia,XIONG Yu,QIAN Shuo. THz Spectra of KDP Crystal[J]. optics&optoelectronic technology, 2012, 0(1): 84-87
Authors:CUI De-yong  ZHANG Xiao-xia  XIONG Yu  QIAN Shuo
Affiliation:(School of Optoelectronic Information,University of Electronic Science and Technology of China,Chengdu 610054,China
Abstract:THz time domain spectrurn of KH2 PO4 crystal in the range from 0. 2 to 1.6 THz, the far-infrared spectrum in the range from 50~4 000 cm 1, and ultraviolet-visible-infrared spectrum in the range from 200~2 000 nm are measured at the room temperature.The energy band gap Eg of KH2 PO4 crystal is 5.91 eV. There is a wide band of the phonon absorption in the KDP crystal.The values of the absorption coefficient are 35~80 cm-1 in the range from 0. 2 to 205.5 THz. The end of the low frequency of the optical phonon model is smaller than 0. 2 THz. The highest frequency νLO of the longitudinal optical phonon model LO is about 205.5 THz, and the force constant κ of H—O ionic chemical bond stretch vibration from the ωLO is calculated to be 13.13 N·cm-1.
Keywords:THz spectrum  infrared-ultraviolet spectrum,KH2PO4 crystal  phonon absorption
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