New one-step procedure for the synthesis of 6H-chromeno[4,3-b]quinolines and 8a,9,14,14a-tetrahydro-8H-benzo[5,6]chromeno[4,3-b]quinolines |
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Authors: | M. M. Tomashevskaya O. A. Tomashenko A. A. Tomashevskii V. V. Sokolov A. A. Potekhin |
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Affiliation: | (1) St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia |
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Abstract: | Schiff bases generated in situ from substituted anilines and 2-allyloxybenzaldehyde underwent acid-catalyzed intramolecular Diels-Alder reaction followed by dehydrogenation to give 6H-chromeno[4,3-b]-quinolines. Under analogous conditions, derivatives of 2-allyloxynaphthalene-1-carbaldehyde were converted into 8a,9,14,14a-tetrahydro-8H-benzo[5,6]chromeno[4,3-b]quinolines. Possible dehydrogenation mechanisms are discussed. Original Russian Text ? M.M. Tomashevskaya, O.A. Tomashenko, A.A. Tomashevskii, V.V. Sokolov, A.A. Potekhin, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 1, pp. 75–80. |
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